________________________________________

THE MARINE MAMMAL COMMISSION COMPENDIUM

MULTILATERAL / MARINE POLLUTION
Volume(s) 1-3; pages 2014-2027


_________________________________________________

======================================

Amendments to the Annex of the Protocol of 1978 Relating to the International Convention for the Prevention of Pollution from Ships, London, 1989


________________________________


Done at London 17 March 1989


Entered into force 13 October 1990


Primary source citation: Copy of text provided by the International Maritime Organization


_________________________________________

AMENDMENTS TO APPENDICES II AND III OF ANNEX II OF MARPOL 73/78

The lists contained in Appendices II and III of Annex II of MARPOL 73/78 are replaced by the following:

APPENDIX II

Pollution Category in brackets indicates that the substance has been provisionally included in this list and that further data are necessary in order to complete the evaluation of its environmental hazards, particularly in relation to living resources. Until the hazard evaluation is completed the Pollution Category assigned shall be used.


Substance

I

II

III

IV

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 


Acetaldehyde


1089

C

 

 

 

 

 

 

 


Acetic acid


2789

D

 

 

 

 

 

 

 


Acetic anhydride

 

D

 

 

 

 

 

 

 


Acetone cyanohydrin


1541

A

0.1

0.05

 

 

 

 

 


Acrylamide solution (50% or less)


2074

D

 

 

 

 

 

 

 


Acrylic acid


2218

D

 

 

 

 

 

 

 


Acrylonitrile


1093

B

 

 

 

 

 

 

 


Adiponitrile


2205

D

 

 

 

 

 

 

 


Alcohol (C12-C15) poly(1-3)ethoxylates

 

A

0.1

0.05

 

 

 

 

 


Alcohol (C12-C15) poly(3-11)ethoxylates

 

A

0.1

0.05

 

 

 

 

 


Alcohol (C6-C17) (secondary) poly(3-6)ethoxylates

 

A

0.1

0.05

 

 

 

 

 


Alcohol (C6-C17) (secondary) poly(7-12)ethoxylates

 

B

 

 

 

 

 

 

 


Alkyl acrylate-Vinyl pyridine copolymer in toluene

 

C

 

 

 

 

 

 

 


Alkyl (C9-C17) benzenes

 

(D)

 

 

 

 

 

 

 


Alkyl benzene sulphonic acid


2584, 2586

C

 

 

 

 

 

 

 


Alkyl benzene sulphonic acid, sodium salt solution

 

C

 

 

 

 

 

 

 


Allyl alcohol


1098

B

 

 

 

 

 

 

 


Allyl chloride


1100

B

 

 

 

 

 

 

 


Aluminium chloride (30% or less)/Hydrochloric acid (20% or less) solution

 

D

 

 

 

 

 

 

 


Aluminium sulphate solution

 

D

 

 

 

 

 

 

 


2-(2-Aminoethoxy) ethanol


3055

D

 

 

 

 

 

 

 


Aminoethyl ethanolamine

 

(D)

 

 

 

 

 

 

 


N-Aminoethylpiperazine


2815

D

 

 

 

 

 

 

 


2-Amino-2-methyl-1-propanol (90% or less)

 

D

 

 

 

 

 

 

 


Ammonia aqueous (28% or less)


2672*

C

 

 

 

 

 

 

 


Ammonium nitrate solution (93% or less)

 

D

 

 

 

 

 

 

 


Ammonium sulphate solution

 

D

 

 

 

 

 

 

 


Ammonium sulphide solution (45% or less)


2683

B

 

 

 

 

 

 

 


Ammonium thiocyanate (25% or less)/Ammonium thiosulphate (20% or less) solution

 

(C)

 

 

 

 

 

 

 


Ammonium thiosulphate solution (60% or less)

 

(C)

 

 

 

 

 

 

 


n-Amyl acetate


1104

C

 

 

 

 

 

 

 


sec-Amyl acetate


1104

C

 

 

 

 

 

 

 


Amyl acetate, commercial


1104

C

 

 

 

 

 

 

 


n-Amyl alcohol


1105

D

 

 

 

 

 

 

 


sec-Amyl alcohol


1105

D

 

 

 

 

 

 

 


Amyl alcohol, primary


1105

D

 

 

 

 

 

 

 


Aniline


1547

C

 

 

 

 

 

 

 


Animal and fish oils, n.o.s. including: Cod liver oil, Sperm oil

 

D

 

 

 

 

 

 

 


Aviation alkylates (C8 paraffins and iso-paraffins BPT 95-120C)

 

(C)

 

 

 

 

 

 

 


Benzene and mixtures having 10% benzene or more


1114**

C

 

 

 

 

 

 

 


Benzene sulphonyl chloride


2225

D

 

 

 

 

 

 

 


Benzyl acetate

 

C

 

 

 

 

 

 

 


Benzyl alcohol

 

C

 

 

 

 

 

 

 


Benzyl chloride


1738

B

 

 

 

 

 

 

 


Brake fluid base mix: (Poly(2-8) alkylene (C2-C3) glycols/Polyalkylene (C2-C10) glycols monoalkyl (C1-C4) ethers and their borate esters)

 

D

 

 

 

 

 

 

 


Butene oligomer

 

B

 

 

 

 

 

 

 


n-Butyl acetate


1123

C

 

 

 

 

 

 

 


sec-Butyl acetate


1123

D

 

 

 

 

 

 

 


n-Butyl acrylate


2348

B

 

 

 

 

 

 

 


Butylamine (all isomers)

 

C

 

 

 

 

 

 

 


Butylbenzenes (all isomers)


2709

(A)

0.1

0.05

 

 

 

 

 


Butyl benzyl phthalate

 

A

0.1

0.05

 

 

 

 

 


n-Butyl butyrate

 

(C)

 

 

 

 

 

 

 


Butyl/Decyl/Cetyl/Eicosyl methacrylate mixture

 

D

 

 

 

 

 

 

 


Butylene glycol

 

D

 

 

 

 

 

 

 


1,2-Butylene oxide


3022

C

 

 

 

 

 

 

 


n-Butyl ether


1149

C

 

 

 

 

 

 

 


Butyl lactate

 

D

 

 

 

 

 

 

 


Butyl methacrylate

 

D

 

 

 

 

 

 

 


n-Butyraldehyde


1129

B

 

 

 

 

 

 

 


Butyric acid


2820

D

 

 

 

 

 

 

 


gamma-Butyrolactone

 

D

 

 

 

 

 

 

 


Calcium alkyl salicylate

 

C

 

 

 

 

 

 

 


Calcium hydroxide slurry

 

D

 

 

 

 

 

 

 


Calcium hypochlorite solution (15% or less)

 

C

 

 

 

 

 

 

 


Calcium hypochlorite solution (more than 15%)

 

B

 

 

 

 

 

 

 


Calcium naphthenate in mineral oil

 

A

0.1

0.05

 

 

 

 

 


Camphor oil


1130

B

 

 

 

 

 

 

 


epsilon-Caprolactam (molten or aqueous solutions)

 

D

 

 

 

 

 

 

 


Carbolic oil

 

A

0.1

0.05

 

 

 

 

 


Carbon disulphide


1131

B

 

 

 

 

 

 

 


Carbon tetrachloride


1846

B

 

 

 

 

 

 

 


Cashew nut shell oil (untreated)

 

D

 

 

 

 

 

 

 


Chlorinated paraffins (C10-C13)

 

A

0.1

0.05

 

 

 

 

 


Chloroacetic acid (80% or less)


1750

C

 

 

 

 

 

 

 


Chlorobenzene


1134

B

 

 

 

 

 

 

 


Chloroform


1888

B

 

 

 

 

 

 

 


Chlorohydrins (crude)

 

(D)

 

 

 

 

 

 

 


o-Chloronitrobenzene


1578

B

 

 

 

 

 

 

 


2- or 3-Chloropropionic acid

 

(C)

 

 

 

 

 

 

 


Chlorosulphonic acid


1754

C

 

 

 

 

 

 

 


m-Chlorotoluene


2238

B

 

 

 

 

 

 

 


o-Chlorotoluene


2238

A

0.1

0.05

 

 

 

 

 


p-Chlorotoluene


2238

B

 

 

 

 

 

 

 


Chlorotoluenes (mixed isomers)


2238

A

0.1

0.05

 

 

 

 

 


Choline chloride solutions

 

D

 

 

 

 

 

 

 


Citric acid

 

D

 

 

 

 

 

 

 


Coal tar

 

A

0.1

0.05

 

 

 

 

 


Coal tar naphtha solvent

 

B

 

 

 

 

 

 

 


Coal tar pitch (molten)

 

D

 

 

 

 

 

 

 


Cobalt naphthenate in solvent naphtha

 

A

0.1

0.05

 

 

 

 

 


Coconut oil fatty acid

 

C

 

 

 

 

 

 

 


Coconut oil fatty acid methyl ester

 

D

 

 

 

 

 

 

 


Creosote (coal tar)

 

A

0.1

0.05

 

 

 

 

 


Creosote (wood)

 

A

0.1

0.05

 

 

 

 

 


Cresols (all isomers)


2076

A

0.1

0.05

 

 

 

 

 


Cresylic acid, sodium salt solution

 

A

0.1

0.05

 

 

 

 

 


Crotonaldehyde


1143

B

 

 

 

 

 

 

 


Cycloheptane


2241

(C)

 

 

 

 

 

 

 


Cyclohexane


1145

C

 

 

 

 

 

 

 


Cyclohexanol

 

C

 

 

 

 

 

 

 


Cyclohexanone


1915

D

 

 

 

 

 

 

 


Cyclohexyl acetate

 

(B)

 

 

 

 

 

 

 


Cyclohexylamine


2357

C

 

 

 

 

 

 

 


1,3-Cyclopentadiene dimer (molten)

 

B

 

 

 

 

 

 

 


Cyclopentane


1146

(C)

 

 

 

 

 

 

 


Cyclopentene

 

(B)

 

 

 

 

 

 

 


p-Cymene


2046

C

 

 

 

 

 

 

 


Decahydronaphthalene


1147

(D)

 

 

 

 

 

 

 


Decanoic acid

 

C

 

 

 

 

 

 

 


Decene

 

B

 

 

 

 

 

 

 


Decyl acrylate

 

A

0.1

0.05

 

 

 

 

 


Decyl alcohol (all isomers)

 

B

 

 

 

 

 

 

 


Decylbenzene

 

D

 

 

 

 

 

 

 


Diacetone alcohol


1148

D

 

 

 

 

 

 

 


Dialkyl (C7-C13) phthalates

 

D

 

 

 

 

 

 

 


Dibutylamine

 

C

 

 

 

 

 

 

 


Dibutyl phthalate

 

A

0.1

0.05

 

 

 

 

 


Dichlorobenzenes (all isomers)


1592

B

 

 

 

 

 

 

 


1,1-Dichloroethane


2362

B

 

 

 

 

 

 

 


Dichloroethyl ether


1916

B

 

 

 

 

 

 

 


1,6-Dichlorohexane

 

B

 

 

 

 

 

 

 


2,2'-Dichloroisopropyl ether


2490

C

 

 

 

 

 

 

 


Dichloromethane


1593

D

 

 

 

 

 

 

 


2,4-Dichlorophenol


2021

A

0.1

0.05

 

 

 

 

 


2,4-Dichlorophenoxyacetic acid, diethanolamine salt solution

 

A

0.1

0.05

 

 

 

 

 


2,4-Dichlorophenoxyacetic acid, dimethylamine salt solution (70% or less)

 

A

0.1

0.05

 

 

 

 

 


2,4-Dichlorophenoxyacetic acid, triisopropanolamine salt solution

 

A

0.1

0.05

 

 

 

 

 


1,1-Dichloropropane

 

B

 

 

 

 

 

 

 


1,2-Dichloropropane


1279

B

 

 

 

 

 

 

 


1,3-Dichloropropane

 

B

 

 

 

 

 

 

 


1,3-Dichloropropene


2047

B

 

 

 

 

 

 

 


Dichloropropene/Dichloropropane mixtures

 

B

 

 

 

 

 

 

 


2,2-Dichloropropionic acid

 

D

 

 

 

 

 

 

 


Diethylamine


1154

C

 

 

 

 

 

 

 


Diethylaminoethanol


2686

C

 

 

 

 

 

 

 


Diethylbenzene


2049

C

 

 

 

 

 

 

 


Diethylene glycol butyl ether acetate

 

(D)

 

 

 

 

 

 

 


Diethylene glycol dibutyl ether

 

D

 

 

 

 

 

 

 


Diethylene glycol ethyl ether acetate

 

(D)

 

 

 

 

 

 

 


Diethylene glycol methyl ether

 

C

 

 

 

 

 

 

 


Diethylene glycol methyl ether acetate

 

(D)

 

 

 

 

 

 

 


Diethylenetriamine


2079

D

 

 

 

 

 

 

 


Di-(2-ethylhexyl) adipate

 

D

 

 

 

 

 

 

 


Di-(2-ethylhexyl) phosphoric acid


1902

C

 

 

 

 

 

 

 


Diethyl phthalate

 

C

 

 

 

 

 

 

 


Diethyl sulphate


1594

(B)

 

 

 

 

 

 

 


Diglycidyl ether of bisphenol A

 

B

 

 

 

 

 

 

 


Diglycidyl ether of bisphenol F

 

B

 

 

 

 

 

 

 


Di-n-hexyl adipate

 

B

 

 

 

 

 

 

 


1,4-Dihydro-9,10-dihydroxy anthracene, disodium salt solution

 

D

 

 

 

 

 

 

 


Diisobutylamine


2361

(C)

 

 

 

 

 

 

 


Diisobutylene


2050

B

 

 

 

 

 

 

 


Diisobutyl ketone


1157

D

 

 

 

 

 

 

 


Diisobutyl phthalate

 

B

 

 

 

 

 

 

 


Diisodecyl phthalate

 

D

 

 

 

 

 

 

 


Diisononyl adipate

 

D

 

 

 

 

 

 

 


Diisopropanolamine

 

C

 

 

 

 

 

 

 


Diisopropylamine


1158

C

 

 

 

 

 

 

 


Diisopropylbenzene (all isomers)

 

A

0.1

0.05

 

 

 

 

 


Diisopropyl naphthalene

 

D

 

 

 

 

 

 

 


N,N-Dimethylacetamide solution (40% or less)

 

D

 

 

 

 

 

 

 


Dimethyl adipate

 

B

 

 

 

 

 

 

 


Dimethylamine solution (45% or less)


1160

C

 

 

 

 

 

 

 


Dimethylamine solution (greater than 45% but not greater than 55%)


1160

C

 

 

 

 

 

 

 


Dimethylamine solution (greater than 55% but not greater than 65%)


1160

C

 

 

 

 

 

 

 


N,N-Dimethylcyclohexylamine


2264

C

 

 

 

 

 

 

 


Dimethylethanolamine


2051

D

 

 

 

 

 

 

 


Dimethylformamide


2265

D

 

 

 

 

 

 

 


Dimethyl glutarate

 

C

 

 

 

 

 

 

 


Dimethyl octanoic acid

 

(C)

 

 

 

 

 

 

 


Dimethyl phthalate

 

C

 

 

 

 

 

 

 


2,2-Dimethylpropane-1,3-diol

 

(D)

 

 

 

 

 

 

 


Dimethyl succinate

 

C

 

 

 

 

 

 

 


Dinitrotoluene (molten)


1600

B

 

 

 

 

 

 

 


Dinonyl phthalate

 

D

 

 

 

 

 

 

 


1,4-Dioxane


1165

D

 

 

 

 

 

 

 


Dipentene


2052

C

 

 

 

 

 

 

 


Diphenyl

 

A

0.1

0.05

 

 

 

 

 


Diphenyl/Diphenyl ether mixtures

 

A

0.1

0.05

 

 

 

 

 


Diphenyl ether

 

A

0.1

0.05

 

 

 

 

 


Diphenyl ether/Diphenyl phenyl ether mixture

 

A

0.1

0.05

 

 

 

 

 


Diphenylmethane diisocyanate


2489

(B)

 

 

 

 

 

 

 


Diphenylol propane-epichlorohydrin resins

 

B

 

 

 

 

 

 

 


Di-n-propylamine


2383

C

 

 

 

 

 

 

 


Dipropylene glycol methyl ether

 

(D)

 

 

 

 

 

 

 


Ditridecyl phthalate

 

D

 

 

 

 

 

 

 


Diundecyl phthalate

 

D

 

 

 

 

 

 

 


Dodecene (all isomers)

 

(B)

 

 

 

 

 

 

 


Dodecenyl succinic acid, dipotassium salt solution

 

(D)

 

 

 

 

 

 

 


Dodecyl alcohol

 

B

 

 

 

 

 

 

 


Dodecyl diphenyl ether disulphonate solution

 

B

 

 

 

 

 

 

 


Dodecyl phenol

 

A

0.1

0.05

 

 

 

 

 


Drilling brines, containing Zinc salts

 

(A)

0.1

0.05

 

 

 

 

 


Epichlorohydrin


2023

C

 

 

 

 

 

 

 


Ethanolamine


2491

D

 

 

 

 

 

 

 


2-Ethoxyethanol


1171

D

 

 

 

 

 

 

 


2-Ethoxyethyl acetate


1172

C

 

 

 

 

 

 

 


Ethyl acetate


1173

D

 

 

 

 

 

 

 


Ethyl acetoacetate

 

(D)

 

 

 

 

 

 

 


Ethyl acrylate


1917

A

0.1

0.05

 

 

 

 

 


Ethylamine


1036

(C)

 

 

 

 

 

 

 


Ethylamine solutions (72% or less)


2270

(C)

 

 

 

 

 

 

 


Ethyl amyl ketone


2271

C

 

 

 

 

 

 

 


Ethylbenzene


1175

C

 

 

 

 

 

 

 


N-Ethylbutylamine

 

(C)

 

 

 

 

 

 

 


Ethyl butyrate


1180

C

 

 

 

 

 

 

 


Ethylcyclohexane

 

(C)

 

 

 

 

 

 

 


N-Ethylcyclohexylamine

 

D

 

 

 

 

 

 

 


Ethylene chlorohydrin


1135

C

 

 

 

 

 

 

 


Ethylene cyanohydrin

 

(D)

 

 

 

 

 

 

 


Ethylenediamine


1604

C

 

 

 

 

 

 

 


Ethylenediamine, Tetraacetic acid, Tetrasodium salt solution

 

D

 

 

 

 

 

 

 


Ethylene dibromide


1605

B

 

 

 

 

 

 

 


Ethylene dichloride


1184

B

 

 

 

 

 

 

 


Ethylene glycol

 

D

 

 

 

 

 

 

 


Ethylene glycol acetate

 

(D)

 

 

 

 

 

 

 


Ethylene glycol butyl ether acetate

 

(C)

 

 

 

 

 

 

 


Ethylene glycol diacetate

 

C

 

 

 

 

 

 

 


Ethylene glycol isopropyl ether

 

D

 

 

 

 

 

 

 


Ethylene glycol methyl butyl ether

 

D

 

 

 

 

 

 

 


Ethylene glycol methyl ether


1188

D

 

 

 

 

 

 

 


Ethylene glycol methyl ether acetate


1189

D

 

 

 

 

 

 

 


Ethylene glycol phenyl ether

 

D

 

 

 

 

 

 

 


Ethylene glycol phenyl ether/Diethylene glycol phenyl ether mixture

 

D

 

 

 

 

 

 

 


Ethylene oxide/Propylene oxide mixture with an Ethylene oxide content of not more than 30% in weight


2983

D

 

 

 

 

 

 

 


2-Ethylhexanoic acid

 

D

 

 

 

 

 

 

 


2-Ethylhexyl acrylate

 

B

 

 

 

 

 

 

 


2-Ethylhexylamine


2276

B

 

 

 

 

 

 

 


Ethylidene norbornene

 

B

 

 

 

 

 

 

 


Ethyl methacrylate


2277

(D)

 

 

 

 

 

 

 


o-Ethylphenol

 

(A)

0.1

0.05

 

 

 

 

 


Ethyl propionate


1195

D

 

 

 

 

 

 

 


2-Ethyl-3-propylacrolein

 

(B)

 

 

 

 

 

 

 


Ethyltoluene

 

(B)

 

 

 

 

 

 

 


Ferric chloride solutions


2582

C

 

 

 

 

 

 

 


Ferric hydroxyethyl ethylenediamine triacetic acid, trisodium salt solution

 

D

 

 

 

 

 

 

 


Ferric nitrate/Nitric acid solution

 

C

 

 

 

 

 

 

 


Formaldehyde solutions (45% or less)


1198, 2209

C

 

 

 

 

 

 

 


Formamide

 

D

 

 

 

 

 

 

 


Formic acid


1779

D

 

 

 

 

 

 

 


Fumaric adduct of rosin, water dispersion

 

B

 

 

 

 

 

 

 


Furfural


1199

C

 

 

 

 

 

 

 


Furfuryl alcohol


2874

C

 

 

 

 

 

 

 


Glutaraldehyde solutions (50% or less)

 

D

 

 

 

 

 

 

 


Glycidyl ester of C10 trialkylacetic acid

 

B

 

 

 

 

 

 

 


Glyoxal solution (40% or less)

 

D

 

 

 

 

 

 

 


Heptane (all isomers)


1206

(C)

 

 

 

 

 

 

 


n-Heptanoic acid

 

(D)

 

 

 

 

 

 

 


Heptanol (all isomers)

 

C

 

 

 

 

 

 

 


Heptene (all isomers)

 

C

 

 

 

 

 

 

 


Heptyl acetate

 

(B)

 

 

 

 

 

 

 


Hexamethylenediamine adipate (50% in water)

 

D

 

 

 

 

 

 

 


Hexamethylenediamine solution


1783

C

 

 

 

 

 

 

 


Hexamethyleneimine


2493

C

 

 

 

 

 

 

 


Hexamethylenetetramine solutions

 

D

 

 

 

 

 

 

 


Hexane (all isomers)


1208

(C)

 

 

 

 

 

 

 


Hexanoic acid

 

D

 

 

 

 

 

 

 


Hexanol


2282

D

 

 

 

 

 

 

 


Hexene (all isomers)

 

(C)

 

 

 

 

 

 

 


Hexyl acetate


1233

B

 

 

 

 

 

 

 


Hydrochloric acid


1789

D

 

 

 

 

 

 

 


Hydrogen peroxide solutions (over 8% but not over 60%)


2014, 2984

C

 

 

 

 

 

 

 


Hydrogen peroxide solutions (over 60% but not over 70%)


2015

C

 

 

 

 

 

 

 


2-Hydroxyethyl acrylate

 

B

 

 

 

 

 

 

 


N-(Hydroxyethyl) ethylenediamine triacetic acid, trisodium salt solution

 

D

 

 

 

 

 

 

 


Isoamyl acetate


1104

C

 

 

 

 

 

 

 


Isoamyl alcohol


1105

D

 

 

 

 

 

 

 


Isobutyl acetate


1213

C

 

 

 

 

 

 

 


Isobutyl acrylate


2527

B

 

 

 

 

 

 

 


Isobutyl formate


2393

D

 

 

 

 

 

 

 


Isobutyraldehyde


2045

C

 

 

 

 

 

 

 


Isophorone

 

D

 

 

 

 

 

 

 


Isophoronediamine


2289

D

 

 

 

 

 

 

 


Isophorone diisocyanate


2290

B

 

 

 

 

 

 

 


Isoprene


1218

C

 

 

 

 

 

 

 


Isopropanolamine

 

C

 

 

 

 

 

 

 


Isopropylamine


1221

C

 

 

 

 

 

 

 


Isopropylbenzene


1918

B

 

 

 

 

 

 

 


Isopropylcyclohexane

 

(C)

 

 

 

 

 

 

 


Isopropyl ether


1159

D

 

 

 

 

 

 

 


Isovaleraldehyde


2058

C

 

 

 

 

 

 

 


Lactic acid

 

D

 

 

 

 

 

 

 


Lactonitrile solution (80% or less)

 

B

 

 

 

 

 

 

 


Latex (ammonia inhibited)

 

D

 

 

 

 

 

 

 


Lauric acid

 

B

 

 

 

 

 

 

 


Maleic anhydride


2215

D

 

 

 

 

 

 

 


Mercaptobenzothiazol, sodium salt solution

 

B

 

 

 

 

 

 

 


Mesityl oxide


1229

D

 

 

 

 

 

 

 


Metam sodium solution

 

A

0.1

0.05

 

 

 

 

 


Methacrylic acid


2531

D

 

 

 

 

 

 

 


Methacrylic resin in 1,2-Dichloroethane solution

 

B

 

 

 

 

 

 

 


Methacrylonitrile


3079

(B)

 

 

 

 

 

 

 


3-Methoxybutyl acetate


2708

D

 

 

 

 

 

 

 


Methyl acetoacetate

 

D

 

 

 

 

 

 

 


Methyl acrylate


1919

B

 

 

 

 

 

 

 


Methylamine solutions (42% or less)


1235

C

 

 

 

 

 

 

 


Methylamyl acetate


1233

(C)

 

 

 

 

 

 

 


Methylamyl alcohol


2053

(C)

 

 

 

 

 

 

 


Methyl amyl ketone


1110

(C)

 

 

 

 

 

 

 


Methyl butenol

 

(D)

 

 

 

 

 

 

 


Methyl tert-butyl ether


2398

D

 

 

 

 

 

 

 


Methyl butyl ketone

 

D

 

 

 

 

 

 

 


Methyl butynol

 

D

 

 

 

 

 

 

 


Methyl butyrate


1237

(C)

 

 

 

 

 

 

 


Methylcyclohexane


2296

(C)

 

 

 

 

 

 

 


Methylcyclopentadiene dimer

 

(B)

 

 

 

 

 

 

 


2-Methyl-6-ethyl aniline

 

C

 

 

 

 

 

 

 


2-Methyl-5-ethyl pyridine


2300

(B)

 

 

 

 

 

 

 


Methyl formate


1243

D

 

 

 

 

 

 

 


Methyl heptyl ketone

 

B

 

 

 

 

 

 

 


Methyl isobutyl ketone


1245

D

 

 

 

 

 

 

 


Methyl methacrylate


1247

D

 

 

 

 

 

 

 


Methylnapthalene

 

A

0.1

0.05

 

 

 

 

 


2-Methyl-1-pentene


2288

C

 

 

 

 

 

 

 


Methyl propyl ketone

 

D

 

 

 

 

 

 

 


2-Methylpyridine


2313

B

 

 

 

 

 

 

 


4-Methylpyridine


2313

B

 

 

 

 

 

 

 


N-Methyl-2-pyrrolidone

 

B

 

 

 

 

 

 

 


Methyl salicylate

 

(B)

 

 

 

 

 

 

 


alpha-Methylstyrene


2303

A

0.1

0.05

 

 

 

 

 


Morpholine


2054

D

 

 

 

 

 

 

 


Motor fuel anti-knock compounds


1649

A

0.1

0.05

 

 

 

 

 


Naphthalene (molten)


2304

A

0.1

0.05

 

 

 

 

 


Naphthalene sulphonic acid-formaldehyde copolymer, sodium salt solution

 

D

 

 

 

 

 

 

 


Naphthenic acids

 

A

0.1

0.05

 

 

 

 

 


Neodecanoic acid

 

C

 

 

 

 

 

 

 


Nitrating acid (mixture of sulphuric and nitric acids)


1796

(C)

 

 

 

 

 

 

 


Nitric acid (less than 70%)


2031

C

 

 

 

 

 

 

 


Nitric acid (70% and over)


2031, 2032

C

 

 

 

 

 

 

 


Nitrilotriacetic acid, trisodium salt solution

 

D

 

 

 

 

 

 

 


Nitrobenzene


1662

B

 

 

 

 

 

 

 


o-Nitrophenol (molten)


1663

B

 

 

 

 

 

 

 


1- or 2-Nitropropane


2608

D

 

 

 

 

 

 

 


Nitropropane (60%)/Nitroethane (40%) mixture


1993

D

 

 

 

 

 

 

 


o- or p-Nitrotoluenes


1664

C

 

 

 

 

 

 

 


Nonane (all isomers)


1920

(C)

 

 

 

 

 

 

 


Nonanoic acid (all isomers)

 

D

 

 

 

 

 

 

 


Nonene

 

B

 

 

 

 

 

 

 


Nonyl alcohol (all isomers)

 

C

 

 

 

 

 

 

 


Nonyl methacrylate monomer

 

(D)

 

 

 

 

 

 

 


Nonylphenol

 

A

0.1

0.05

 

 

 

 

 


Nonyl phenol poly(4-12)ethoxylates

 

B

 

 

 

 

 

 

 


Octane (all isomers)


1262

(C)

 

 

 

 

 

 

 


Octanoic acid (all isomers)

 

D

 

 

 

 

 

 

 


Octanol (all isomers)

 

C

 

 

 

 

 

 

 


Octene (all isomers)

 

B

 

 

 

 

 

 

 


n-Octyl acetate

 

D

 

 

 

 

 

 

 


Octyl aldehydes

 

(B)

 

 

 

 

 

 

 


Octyl nitrates (all isomers)

 

A

0.1

0.05

 

 

 

 

 


Olefin mixtures (C5-C7)

 

C

 

 

 

 

 

 

 


Olefin mixtures (C5-C15)

 

B

 

 

 

 

 

 

 


alpha-Olefins (C6-C18) mixtures

 

B

 

 

 

 

 

 

 


Oleic acid

 

D

 

 

 

 

 

 

 


Oleum


1831

C

 

 

 

 

 

 

 


Palm nut oil fatty acid

 

(C)

 

 

 

 

 

 

 


Palm oil fatty acid methyl ester

 

D

 

 

 

 

 

 

 


Palm stearin

 

D

 

 

 

 

 

 

 


Paraldehyde


1264

C

 

 

 

 

 

 

 


Pentachloroethane


1669

B

 

 

 

 

 

 

 


1,3-Pentadiene

 

C

 

 

 

 

 

 

 


Pentaethylenehexamine

 

D

 

 

 

 

 

 

 


Pentane (all isomers)


1265

(C)

 

 

 

 

 

 

 


Pentanoic acid

 

D

 

 

 

 

 

 

 


Pentene (all isomers)

 

C

 

 

 

 

 

 

 


Perchloroethylene


1897

B

 

 

 

 

 

 

 


Phenol


2312

B

 

 

 

 

 

 

 


1-Phenyl-1-xylyl ethane

 

C

 

 

 

 

 

 

 


Phosphoric acid


1805

D

 

 

 

 

 

 

 


Phosphorus, yellow or white


1381, 2447

A

0.01

0.005

 

 

 

 

 


Phthalic anhydride (molten)


2214

C

 

 

 

 

 

 

 


Pinene


2368

B

 

 

 

 

 

 

 


Polyalkylene glycol butyl ether

 

D

 

 

 

 

 

 

 


Polyethylene polyamines


2734, 2735

(C)

 

 

 

 

 

 

 


Polyferric sulphate solution

 

(C)

 

 

 

 

 

 

 


Polymethylene polyphenyl isocyanate


2207

D

 

 

 

 

 

 

 


Polypropylene glycol

 

D

 

 

 

 

 

 

 


Potassium hydroxide solution


1814

C

 

 

 

 

 

 

 


n-Propanolamine

 

C

 

 

 

 

 

 

 


beta-Propiolactone

 

D

 

 

 

 

 

 

 


Propionaldehyde


1275

D

 

 

 

 

 

 

 


Propionic acid


1848

D

 

 

 

 

 

 

 


Propionic anhydride


2496

C

 

 

 

 

 

 

 


Propionitrile


2404

C

 

 

 

 

 

 

 


n-Propyl acetate


1276

D

 

 

 

 

 

 

 


n-Propylamine


1277

C

 

 

 

 

 

 

 


n-Propylbenzene


2364

(C)

 

 

 

 

 

 

 


n-Propyl chloride

 

B

 

 

 

 

 

 

 


Propylene dimer

 

(C)

 

 

 

 

 

 

 


Propylene glycol ethyl ether

 

(D)

 

 

 

 

 

 

 


Propylene glycol methyl ether

 

(D)

 

 

 

 

 

 

 


Propylene glycol monoalkyl ether

 

(D)

 

 

 

 

 

 

 


Propylene oxide


1280

D

 

 

 

 

 

 

 


Propylene tetramer


2850

B

 

 

 

 

 

 

 


Propylene trimer


2057

B

 

 

 

 

 

 

 


Pyridine


1282

D

 

 

 

 

 

 

 


Rosin

 

B

 

 

 

 

 

 

 


Rosin soap (disproportionated) solution

 

B

 

 

 

 

 

 

 


Silicon tetrachloride

 

D

 

 

 

 

 

 

 


Sodium aluminate solution

 

C

 

 

 

 

 

 

 


Sodium borohydride (15% or less)/Sodium hydroxide solution

 

C

 

 

 

 

 

 

 


Sodium carbonate solution

 

D

 

 

 

 

 

 

 


Sodium dichromate solution (70% or less)

 

C

 

 

 

 

 

 

 


Sodium hydrogen sulphite solution (35% or less)


2693

D

 

 

 

 

 

 

 


Sodium hydrosulphide/Ammonium sulphide solution

 

B

 

 

 

 

 

 

 


Sodium hydrosulphide solution (45% or less)


2949

B

 

 

 

 

 

 

 


Sodium hydroxide solution


1824

D

 

 

 

 

 

 

 


Sodium hypochlorite solution (15% or less)


1791

C

 

 

 

 

 

 

 


Sodium nitrite solution


1577

B

 

 

 

 

 

 

 


Sodium silicate solution

 

D

 

 

 

 

 

 

 


Sodium sulphide solution

 

B

 

 

 

 

 

 

 


Sodium sulphite solution

 

C

 

 

 

 

 

 

 


Sodium thiocyanate solution (56% or less)

 

(B)

 

 

 

 

 

 

 


Styrene monomer


2055

B

 

 

 

 

 

 

 


Sulpholane

 

D

 

 

 

 

 

 

 


Sulphuric acid


1830

C

 

 

 

 

 

 

 


Sulphuric acid, spent


1832

C

 

 

 

 

 

 

 


Tall oil (crude and distilled)

 

B

 

 

 

 

 

 

 


Tall oil fatty acid (resin acids less than 20%)

 

(C)

 

 

 

 

 

 

 


Tall oil soap (disproportionated) solution

 

B

 

 

 

 

 

 

 


Tallow

 

D

 

 

 

 

 

 

 


Tallow fatty acid

 

(D)

 

 

 

 

 

 

 


Tetrachloroethane


1702

B

 

 

 

 

 

 

 


Tetraethylene pentamine


2320

D

 

 

 

 

 

 

 


Tetrahydrofuran


2056

D

 

 

 

 

 

 

 


Tetrahydronaphthalene

 

C

 

 

 

 

 

 

 


1,2,3,5-Tetramethylbenzene

 

(C)

 

 

 

 

 

 

 


Titanium tetrachloride


1838

D

 

 

 

 

 

 

 


Toluene


1294

C

 

 

 

 

 

 

 


Toluenediamine


1709

C

 

 

 

 

 

 

 


Toluene diisocyanate


2078

C

 

 

 

 

 

 

 


o-Toluidine


1708

C

 

 

 

 

 

 

 


Tributyl phosphate

 

B

 

 

 

 

 

 

 


1,2,4-Trichlorobenzene


2321

B

 

 

 

 

 

 

 


1,1,1-Trichloroethane


2831

B

 

 

 

 

 

 

 


1,1,2-Trichloroethane

 

B

 

 

 

 

 

 

 


Trichloroethylene


1710

B

 

 

 

 

 

 

 


1,2,3-Trichloropropane

 

B

 

 

 

 

 

 

 


1,1,2-Trichloro-1,2,2-trifluoroethane

 

C

 

 

 

 

 

 

 


Tricresyl phosphate (containing less than 1% ortho-isomer)

 

A

0.1

0.05

 

 

 

 

 


Tricresyl phosphate (containing 1% or more ortho-isomer)


2574[dagger]

A

0.1

0.05

 

 

 

 

 


Triethanolamine

 

D

 

 

 

 

 

 

 


Triethylamine


1296

C

 

 

 

 

 

 

 


Triethylbenzene

 

A

0.1

0.05

 

 

 

 

 


Triethylene glycol ethyl ether

 

(D)

 

 

 

 

 

 

 


Triethylene glycol methyl ether

 

(D)

 

 

 

 

 

 

 


Triethylenetetramine


2259

D

 

 

 

 

 

 

 


Trimethylacetic acid

 

D

 

 

 

 

 

 

 


Trimethylamine

 

C

 

 

 

 

 

 

 


Trimethyl benzenes (all isomers)

 

B

 

 

 

 

 

 

 


Trimethylhexamethylene diamine (2,2,4- and 2,4,4-isomers)


2327

D

 

 

 

 

 

 

 


Trimethylhexamethylene diisocyanate (2,2,4- and 2,4,4-isomers)


2328

B

 

 

 

 

 

 

 


Trimethylol propane polyethoxylate

 

D

 

 

 

 

 

 

 


2,2,4-Trimethyl-1,3-pentanediol-1-isobutyrate

 

C

 

 

 

 

 

 

 


Tripropylene glycol methyl ether

 

(D)

 

 

 

 

 

 

 


Trixylyl phosphate

 

A

0.1

0.05

 

 

 

 

 


Turpentine


1299

B

 

 

 

 

 

 

 


Undecanoic acid

 

(C)

 

 

 

 

 

 

 


1-Undecene

 

B

 

 

 

 

 

 

 


Undecyl alcohol

 

B

 

 

 

 

 

 

 


Urea/Ammonium mono- and di-hydrogen phosphite/Potassium chloride solution

 

(D)

 

 

 

 

 

 

 


Urea/Ammonium nitrate solution

 

D

 

 

 

 

 

 

 


Urea/Ammonium nitrate solution (containing aqua Ammonia)

 

C

 

 

 

 

 

 

 


Urea/Ammonium phosphate solution

 

D

 

 

 

 

 

 

 


n-Valeraldehyde


2058

D

 

 

 

 

 

 

 


Vegetable oil, n.o.s., including: Castor oil, Coconut oil, Corn oil, Cottonseed oil, Groundnut oil, Linseed oil, Olive oil, Palm nut oil, Palm oil, Rape seed oil, Rice bran oil, Safflower oil, Sesame oil, Soya bean oil, Sunflower oil, Tung oil

 

D

 

 

 

 

 

 

 


Vinyl acetate


1301

C

 

 

 

 

 

 

 


Vinyl ethyl ether


1302

C

 

 

 

 

 

 

 


Vinylidene chloride


1303

B

 

 

 

 

 

 

 


Vinyl neodecanoate

 

B

 

 

 

 

 

 

 


Vinyltoluene


2618

A

0.1

0.05

 

 

 

 

 


White spirit, low (15-20%) aromatic


1300

(B)

 

 

 

 

 

 

 


Xylenes


1307

C

 

 

 

 

 

 

 


Xylenol


2261

B

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

* UN number refers to 10-35%.

** UN number 1114 applies to Benzene.

[dagger] UN number 2574 applies to Tricresyl phosphate containing more than 3% ortho-isomer.

APPENDIX III


Substance

UN number

 

 

 

 

 

 


Acetone


1090

 

 


Acetonitrile


1648

 

 


Alcoholic beverages, n.o.s.

 

 

 


Alcohols (C13 and above)

 

 

 


Aminoethyldiethanolamine/Aminoethylethanolamine solution

 

 

 


2-Amino-2-hydroxymethyl-1,3-propanediol solution (40% or less)

 

 

 


tert-Amyl alcohol


1105

 

 


Apple juice

 

 

 


Behenyl alcohol

 

 

 


Benzene tricarboxylic acid, trioctyl ester

 

 

 


n-Butyl alcohol


1120

 

 


sec-Butyl alcohol


1120

 

 


tert-Butyl alcohol


1120

 

 


Butyl stearate

 

 

 


Calcium carbonate slurry

 

 

 


Calcium nitrate/Magnesium nitrate/Potassium chloride solution

 

 

 


Cetyl/Eicosyl methacrylate mixture

 

 

 


Cetyl/Stearyl alcohol

 

 

 


Chlorinated paraffins (C14-C17) (with 52% chlorine)

 

 

 


Clay slurry

 

 

 


Coal slurry

 

 

 


Dextrose solution

 

 

 


Diethanolamine

 

 

 


Diethyl ether


1155

 

 


Diethylene glycol

 

 

 


Diethylene glycol butyl ether

 

 

 


Diethylene glycol diethyl ether

 

 

 


Diethylene glycol ethyl ether

 

 

 


Diethylenetriamine pentaacetic acid, pentasodium salt solution

 

 

 


Diheptyl phthalate

 

 

 


Dihexyl phthalate

 

 

 


Diisooctyl phthalate

 

 

 


Dioctyl phthalate

 

 

 


Dipropylene glycol

 

 

 


Dodecane (all isomers)

 

 

 


Dodecyl benzene

 

 

 


Dodecyl methacrylate

 

 

 


Dodecyl/Pentadecyl methacrylate mixture

 

 

 


Drilling brines: Calcium bromide solution, Calcium chloride solution, Sodium chloride solution

 

 

 


Ethyl alcohol


1170

 

 


Ethylene carbonate

 

 

 


Ethylene glycol butyl ether


2369

 

 


Ethylene glycol tert-butyl ether

 

 

 


Ethylene-Vinyl acetate copolymer (emulsion)

 

 

 


Fatty acid (saturated, C13 and above)

 

 

 


Glucose solution

 

 

 


Glycerine

 

 

 


Glycerol polyalkoxylate

 

 

 


Glyceryl triacetate

 

 

 


Glycine, sodium salt solution

 

 

 


Hexamethylene glycol

 

 

 


Hexylene glycol

 

 

 


Isobutyl alcohol


1212

 

 


Isopropyl acetate


1220

 

 


Isopropyl alcohol


1219

 

 


Kaolin slurry

 

 

 


Lard

 

 

 


Latex: Carboxylated styrene-Butadiene copolymer, Styrene-butadiene rubber

 

 

 


Lignin sulphonic acid, sodium salt solution

 

 

 


Magnesium chloride solution

 

 

 


Magnesium hydroxide slurry

 

 

 


3-Methoxy-1-butanol

 

 

 


Methyl acetate


1231

 

 


Methyl alcohol


1230

 

 


Methyl ethyl ketone

 

 

 


2-Methyl-2-hydroxy-3-butyne

 

 

 


3-Methyl-3-methoxy butanol

 

 

 


3-Methyl-3-methoxy butyl acetate

 

 

 


Molasses

 

 

 


Octyl decyl adipate

 

 

 


alpha-Olefins (C13-C18)

 

 

 


Olefins (C13 and above, all isomers)

 

 

 


n-Paraffins (C10-C20)

 

 

 


Paraffin wax

 

 

 


Petrolatum

 

 

 


Polyaluminium chloride solution

 

 

 


Polybutene

 

 

 


Polyethylene glycol dimethyl ether

 

 

 


Polyethylene glycols

 

 

 


Polypropylene glycol methyl ether

 

 

 


Polysiloxane

 

 

 


n-Propyl alcohol

 

 

 


Propylene glycol

 

 

 


Propylene-butylene copolymer

 

 

 


Sodium alumino silicate slurry

 

 

 


Sodium chlorate solution (50% or less)


2428

 

 


Sorbitol solution

 

 

 


Sulphur (molten)


2448

 

 


Tetraethylene glycol

 

 

 


Tridecane

 

 

 


Tridecanoic acid

 

 

 


Triethylene glycol

 

 

 


Triethylene glycol butyl ether

 

 

 


Triisopropanolamine

 

 

 


Tripropylene glycol

 

 

 


Urea formaldehyde resin solution

 

 

 


Urea solution

 

 

 


Vegetable protein solution (hydrolyzed)

 

 

 


Water

 

 

 


[1] Adopted pursuant to IMO Marine Environment Protection Committee Resolution MEPC.34(27).